Formation of Beryllium Fluoride
  • Category: Science
  • Topic: Biology , Chemistry

The process of forming a bond between two or more atoms can be explained through the Lewis structure of the compound. When drawing a Lewis structure, only the valence electrons of the atom are considered, and they are indicated by dots and lines for bonds. This way of drawing a structure is called a Lewis dot structure.

Lewis dot structures can be drawn for both ionic and covalently bonded compounds. Beryllium fluoride is an inorganic compound that has one beryllium atom and two fluoride atoms. Beryllium belongs to the second group of alkaline earth metals, while fluoride is a member of the halogens.

To draw the Lewis structure of any compound, there are certain rules to follow. First, calculate the total number of valence electrons present in the compound by adding the valence electrons in each atom. For BeF₂, beryllium has 2 valence electrons and fluorine has 7, resulting in 16 electrons.

In BeF₂, one beryllium atom is paired with two fluorine atoms, each with 7 valence electrons. Beryllium shares its two valence electrons with the fluorine atoms to form two Be-F single bonds. Thus, the Lewis structure of BeF₂ is [].

Resonance in BeF₂

Resonance occurs when there is delocalisation of electrons associated with an atom, resulting in multiple structures for a molecule or compound. This process can be observed in double bonded compounds and compounds with a lone pair of electrons. When drawing the resonating structure, the molecular formula of the compound should not change. Since there is no double bond present between beryllium and fluorine in BeF₂, there is no resonance structure for the compound.

Shape and Bond Angle of BeF₂

BeF₂ is formed by sharing electrons between one beryllium atom and two fluorine atoms, producing a linear shape. A linear molecule is one where the atoms are arranged on a straight line, with the two fluorine atoms placed on both sides of beryllium in a straight pattern. The bond angle between the beryllium and fluorine atoms in BeF₂ is 180⁰.

Formal Charge and Octet Rule in BeF₂

The formal charge of an atom is the charge it acquires as a result of its bond formation with another atom. The formula for finding the formal charge of an atom is (Valence electrons – No. of lone pairs – No. of bonds formed). The formal charge of beryllium in BeF₂ is 0, as it has 2 valence electrons and forms 2 bonds with the fluorine atoms. The formal charge of fluorine is also 0, as it has 7 valence electrons, forms 1 bond with beryllium, and has 6 lone pairs. The octet rule states that when atoms combine to form stable compounds, their outermost shell should be filled with eight electrons. In the case of covalent compounds, atoms share electrons to obey the octet rule. In ionic compounds, they either lose or gain electrons to complete their octet.

The lone pair of electrons, also referred to as non-bonding electrons, are electrons that do not participate in bond formation and remain with the atom. Beryllium does not have any lone pair of electrons. On the other hand, Fluorine has three lone pairs of electrons.

Valence electrons, which are associated with an atom that only participates in bond formation, are also crucial to understanding BeF₂. Beryllium has two valence electrons, while Fluorine has seven. Consequently, BeF₂ has a total of 16 valence electrons.

Hybridization is a concept wherein atomic orbitals with different energies combine to generate new orbitals with the same energy and shape. When two different orbitals undergo hybridization, the number of formed orbitals will also be equal. For beryllium fluoride, sp hybridization occurs, resulting in the formation of two sp orbitals with 50% s character and 50% p character, oriented in opposite directions.

Beryllium fluoride has high water solubility and low ethanol solubility.

BeF₂ is a covalent compound with linear shape as it is formed through the sharing of atoms between beryllium and fluorine. It is also a non-polar molecule with a net dipole moment of zero.

BeF₂ is acidic in nature and can be a good Lewis acid since beryllium can accept more electrons.

In summary, BeF₂ is an inorganic compound used as a precursor for the synthesis of beryllium. Its properties include the absence of a lone pair of electrons in beryllium, high water solubility, low ethanol solubility, non-polarity, and acidic behavior.

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